Title |
20 Years of Air–Water Gas Exchange Observations for Pesticides in the Western Arctic Ocean
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Published in |
Environmental Science & Technology, August 2015
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DOI | 10.1021/acs.est.5b01303 |
Pubmed ID | |
Authors |
Liisa M. Jantunen, Fiona Wong, Anya Gawor, Henrik Kylin, Paul A. Helm, Gary A. Stern, William M. J. Strachan, Deborah A. Burniston, Terry F. Bidleman |
Abstract |
The arctic has been contaminated by legacy organochlorine pesticides (OCPs) and currently used pesticides (CUPs) through atmospheric transport and oceanic currents. Here we report time trends and air-water exchange of OCPs and CUPs from research expeditions conducted between 1993-2013. Compounds determined in both air and water were trans- and cis-chlordanes (TC, CC), trans- and cis-nonachlors (TN, CN), heptachlor exo-epoxide (HEPX), dieldrin (DIEL), chlorobornanes (ΣCHBs, toxaphene), dacthal (DAC), endosulfans and metabolite endosulfan sulfate (ENDO-I, ENDO-II, ENDO SUL), chlorothalonil (CHT), chlorpyrifos (CPF) and trifluralin (TFN). Pentachloronitrobenzene (PCNB, quintozene) and its soil metabolite pentachlorothianisole (PCTA) were also found in air. Concentrations of most OCPs declined in surface water, whereas some CUPs increased (ENDO-I, CHT and TFN) or showed no significant change (CPF, DAC), while most compounds declined in air. Chlordane compound fractions TC/(TC+CC) and TC/(TC+CC+TN) decreased in water and air, while CC/(TC+CC+TN) and TN/(TC+CC+TN) increased, suggesting selective removal of more labile TC over time and/or a shift in chlordane sources. Water/air fugacity ratios indicated net volatilization (FR >1.0) or near equilibrium (FR not significantly different from 1.0) for most OCPs, but net deposition (FR <1.0) for ΣCHBs. Net deposition was shown for ENDO-I on all expeditions, while the net exchange direction of other CUPs varied. Understanding the processes and current state of air-surface exchange helps to interpret environmental exposure, evaluate the effectiveness of International Protocols and provides insights for the environmental fate of new and emerging chemicals. |
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Geographical breakdown
Country | Count | As % |
---|---|---|
United States | 3 | 5% |
Canada | 2 | 4% |
Unknown | 51 | 91% |
Demographic breakdown
Readers by professional status | Count | As % |
---|---|---|
Student > Ph. D. Student | 20 | 36% |
Researcher | 7 | 13% |
Student > Bachelor | 4 | 7% |
Other | 3 | 5% |
Student > Master | 3 | 5% |
Other | 6 | 11% |
Unknown | 13 | 23% |
Readers by discipline | Count | As % |
---|---|---|
Environmental Science | 16 | 29% |
Agricultural and Biological Sciences | 8 | 14% |
Chemistry | 4 | 7% |
Engineering | 2 | 4% |
Earth and Planetary Sciences | 2 | 4% |
Other | 4 | 7% |
Unknown | 20 | 36% |