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A new organic reference material, l‐glutamic acid, USGS41a, for δ13C and δ15N measurements − a replacement for USGS41

Overview of attention for article published in Rapid Communications in Mass Spectrometry, March 2016
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Title
A new organic reference material, l‐glutamic acid, USGS41a, for δ13C and δ15N measurements − a replacement for USGS41
Published in
Rapid Communications in Mass Spectrometry, March 2016
DOI 10.1002/rcm.7510
Pubmed ID
Authors

Haiping Qi, Tyler B Coplen, Stanley J Mroczkowski, Willi A Brand, Lauren Brandes, Heike Geilmann, Arndt Schimmelmann

Abstract

The widely used l-glutamic acid isotopic reference material USGS41, enriched in both (13) C and (15) N, is nearly exhausted. A new material, USGS41a, has been prepared as a replacement for USGS41. USGS41a was prepared by dissolving analytical grade l-glutamic acid enriched in (13) C and (15) N together with l-glutamic acid of normal isotopic composition. The δ(13) C and δ(15) N values of USGS41a were directly or indirectly normalized with the international reference materials NBS 19 calcium carbonate (δ(13) CVPDB = +1.95 mUr, where milliurey = 0.001 = 1 ‰), LSVEC lithium carbonate (δ(13) CVPDB = -46.6 mUr), and IAEA-N-1 ammonium sulfate (δ(15) NAir = +0.43 mUr) and USGS32 potassium nitrate (δ(15) N = +180 mUr exactly) by on-line combustion, continuous-flow isotope-ratio mass spectrometry, and off-line dual-inlet isotope-ratio mass spectrometry. USGS41a is isotopically homogeneous; the reproducibility of δ(13) C and δ(15) N is better than 0.07 mUr and 0.09 mUr, respectively, in 200-μg amounts. It has a δ(13) C value of +36.55 mUr relative to VPDB and a δ(15) N value of +47.55 mUr relative to N2 in air. USGS41 was found to be hydroscopic, probably due to the presence of pyroglutamic acid. Experimental results indicate that the chemical purity of USGS41a is substantially better than that of USGS41. The new isotopic reference material USGS41a can be used with USGS40 (having a δ(13) CVPDB value of -26.39 mUr and a δ(15) NAir value of -4.52 mUr) for (i) analyzing local laboratory isotopic reference materials, and (ii) quantifying drift with time, mass-dependent isotopic fractionation, and isotope-ratio-scale contraction for isotopic analysis of biological and organic materials. Published in 2016. This article is a U.S. Government work and is in the public domain in the USA.

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Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 37 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
United Kingdom 1 3%
Canada 1 3%
Unknown 35 95%

Demographic breakdown

Readers by professional status Count As %
Researcher 6 16%
Student > Ph. D. Student 4 11%
Student > Doctoral Student 3 8%
Professor > Associate Professor 3 8%
Student > Master 3 8%
Other 6 16%
Unknown 12 32%
Readers by discipline Count As %
Environmental Science 7 19%
Agricultural and Biological Sciences 5 14%
Earth and Planetary Sciences 4 11%
Chemistry 4 11%
Nursing and Health Professions 1 3%
Other 3 8%
Unknown 13 35%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 2. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 01 March 2016.
All research outputs
#16,151,418
of 24,565,648 outputs
Outputs from Rapid Communications in Mass Spectrometry
#3,101
of 4,897 outputs
Outputs of similar age
#173,024
of 303,771 outputs
Outputs of similar age from Rapid Communications in Mass Spectrometry
#24
of 73 outputs
Altmetric has tracked 24,565,648 research outputs across all sources so far. This one is in the 32nd percentile – i.e., 32% of other outputs scored the same or lower than it.
So far Altmetric has tracked 4,897 research outputs from this source. They receive a mean Attention Score of 3.3. This one is in the 32nd percentile – i.e., 32% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 303,771 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 40th percentile – i.e., 40% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 73 others from the same source and published within six weeks on either side of this one. This one has gotten more attention than average, scoring higher than 63% of its contemporaries.