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Bonding in Electron-Rich Molecules

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Cover of 'Bonding in Electron-Rich Molecules'

Table of Contents

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    Book Overview
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    Chapter 1 Atomic Orbitals, Electron Spin, Linear Combinations
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    Chapter 2 Pauling “3-Electron Bonds”, 4-Electron 3-Centre Bonding, and the Need for an “Increased Valence” Theory
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    Chapter 3 Wave-Functions and Valence-Bond Structures for 1-Electron Bonds, Electron-Pair Bonds, Pauling “3-Electron Bonds” and “no Bonds”
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    Chapter 4 Valence-Bond Structures for some Diatomic and related Molecules
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    Chapter 5 Pauling “3-Electron Bonds” and Hypoligated Transition Metal Complexes
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    Chapter 6 Pauling “3-Electron Bonds”, 5-Electron 3-Centre Bonding and Some Tetra-Atomic Radicals
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    Chapter 7 Some Dimers of Triatomic Radicals with 17 and 19 Valence-Shell Electrons
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    Chapter 8 Some Cu(II) Binuclear Transition-Metal Complexes
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    Chapter 9 Excited States
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    Chapter 10 Pauling “3-Electron Bonds” and “Increased Valence” Theory for N 2 O 4
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    Chapter 11 Pauling “3-Electron Bonds” and “Increased-Valence” Structures
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    Chapter 12 Increased-Valence Structures Constructed from Lewis Structures: Delocalization of a Lone-Pair Electron into a Vacant Bonding Orbital
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    Chapter 13 “Increased-Valence” Structures for N -Centre Bonding Units
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    Chapter 14 Delocalization of a Lone-Pair Electron into a Vacant Antibonding Orbital: Increased-Valence Structures, Molecular Orbital Theory and Atomic Valencies
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    Chapter 15 Slater Determinants and Wave-Functions for “Increased-Valence” Structures
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    Chapter 16 Classical Valence Bond Structures and Quinquevalent Nitrogen Atoms
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    Chapter 17 Some Tetrahedral Molecules and d π – p π Bonding for some Sulphur Compounds
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    Chapter 18 Transition Metal Complexes with CO, N 2 , NO and O 2 Ligands
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    Chapter 19 Some Electron-Excess σ Bonded Systems
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    Chapter 20 Intermolecular Donor-Acceptor Complexes
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    Chapter 21 Base-Displacement Reactions and Electron Conduction in Alkali Metals
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    Chapter 22 Free-Radical and Spin-Paired Diradical Reactions
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    Chapter 23 Some Comparisons of Types of Wave-Funcions for 4-Eelectron 3-Centre Bonding Units
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    Chapter 24 A Note on Pauling “3-Electron Bonds” and Covalent-Ionic Resonance
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    Chapter 25 Some Additional Topics
Attention for Chapter 14: Delocalization of a Lone-Pair Electron into a Vacant Antibonding Orbital: Increased-Valence Structures, Molecular Orbital Theory and Atomic Valencies
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Chapter title
Delocalization of a Lone-Pair Electron into a Vacant Antibonding Orbital: Increased-Valence Structures, Molecular Orbital Theory and Atomic Valencies
Chapter number 14
Book title
Bonding in Electron-Rich Molecules
Published by
Springer, Cham, January 2016
DOI 10.1007/978-3-319-16676-6_14
Book ISBNs
978-3-31-916675-9, 978-3-31-916676-6
Authors

Richard D. Harcourt

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