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Thermal decomposition of [Co(en)3][Fe(CN)6]∙ 2H2O: Topotactic dehydration process, valence and spin exchange mechanism elucidation

Overview of attention for article published in Chemistry Central Journal, February 2013
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Title
Thermal decomposition of [Co(en)3][Fe(CN)6]∙ 2H2O: Topotactic dehydration process, valence and spin exchange mechanism elucidation
Published in
Chemistry Central Journal, February 2013
DOI 10.1186/1752-153x-7-28
Pubmed ID
Authors

Zdeněk Trávníček, Radek Zbořil, Miroslava Matiková-Maľarová, Bohuslav Drahoš, Juraj Černák

Abstract

The Prussian blue analogues represent well-known and extensively studied group of coordination species which has many remarkable applications due to their ion-exchange, electron transfer or magnetic properties. Among them, Co-Fe Prussian blue analogues have been extensively studied due to the photoinduced magnetization. Surprisingly, their suitability as precursors for solid-state synthesis of magnetic nanoparticles is almost unexplored. In this paper, the mechanism of thermal decomposition of [Co(en)3][Fe(CN)6] ∙∙ 2H2O (1a) is elucidated, including the topotactic dehydration, valence and spins exchange mechanisms suggestion and the formation of a mixture of CoFe2O4-Co3O4 (3:1) as final products of thermal degradation.

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X Demographics

The data shown below were collected from the profile of 1 X user who shared this research output. Click here to find out more about how the information was compiled.
Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 19 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
United States 1 5%
Czechia 1 5%
France 1 5%
Unknown 16 84%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 5 26%
Student > Doctoral Student 2 11%
Professor 2 11%
Professor > Associate Professor 2 11%
Researcher 2 11%
Other 1 5%
Unknown 5 26%
Readers by discipline Count As %
Chemistry 7 37%
Physics and Astronomy 2 11%
Computer Science 1 5%
Materials Science 1 5%
Engineering 1 5%
Other 0 0%
Unknown 7 37%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 08 February 2013.
All research outputs
#21,157,205
of 25,986,827 outputs
Outputs from Chemistry Central Journal
#1
of 1 outputs
Outputs of similar age
#233,481
of 295,033 outputs
Outputs of similar age from Chemistry Central Journal
#18
of 34 outputs
Altmetric has tracked 25,986,827 research outputs across all sources so far. This one is in the 10th percentile – i.e., 10% of other outputs scored the same or lower than it.
So far Altmetric has tracked 1 research outputs from this source. They receive a mean Attention Score of 0.5. This one scored the same or higher as 0 of them.
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We're also able to compare this research output to 34 others from the same source and published within six weeks on either side of this one. This one is in the 1st percentile – i.e., 1% of its contemporaries scored the same or lower than it.