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Catalytic Decarboxylative Fluorination for the Synthesis of Tri- and Difluoromethyl Arenes

Overview of attention for article published in Organic Letters, May 2013
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1 tweeter

Citations

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76 Mendeley
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Title
Catalytic Decarboxylative Fluorination for the Synthesis of Tri- and Difluoromethyl Arenes
Published in
Organic Letters, May 2013
DOI 10.1021/ol4009377
Pubmed ID
Authors

Satoshi Mizuta, Ida S. R. Stenhagen, Miriam O’Duill, Jamie Wolstenhulme, Anna K. Kirjavainen, Sarita J. Forsback, Matthew Tredwell, Graham Sandford, Peter R. Moore, Mickael Huiban, Sajinder K. Luthra, Jan Passchier, Olof Solin, Véronique Gouverneur

Abstract

Treatment of readily available α,α-difluoro- and α-fluoroarylacetic acids with Selectfluor under Ag(I) catalysis led to decarboxylative fluorination. This operationally simple reaction gave access to tri- and difluoromethylarenes applying a late-stage fluorination strategy. Translation to [(18)F]labeling is demonstrated using [(18)F]Selectfluor bis(triflate), a reagent affording [(18)F]tri- and [(18)F]difluoromethylarenes not within reach with [(18)F]F2.

Twitter Demographics

The data shown below were collected from the profile of 1 tweeter who shared this research output. Click here to find out more about how the information was compiled.

Mendeley readers

The data shown below were compiled from readership statistics for 76 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Denmark 1 1%
Unknown 75 99%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 34 45%
Researcher 12 16%
Student > Master 8 11%
Student > Bachelor 7 9%
Student > Doctoral Student 6 8%
Other 9 12%
Readers by discipline Count As %
Chemistry 69 91%
Unspecified 7 9%

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 24 May 2013.
All research outputs
#9,830,280
of 12,308,537 outputs
Outputs from Organic Letters
#7,384
of 8,738 outputs
Outputs of similar age
#99,866
of 144,278 outputs
Outputs of similar age from Organic Letters
#128
of 189 outputs
Altmetric has tracked 12,308,537 research outputs across all sources so far. This one is in the 11th percentile – i.e., 11% of other outputs scored the same or lower than it.
So far Altmetric has tracked 8,738 research outputs from this source. They receive a mean Attention Score of 3.9. This one is in the 5th percentile – i.e., 5% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 144,278 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 16th percentile – i.e., 16% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 189 others from the same source and published within six weeks on either side of this one. This one is in the 6th percentile – i.e., 6% of its contemporaries scored the same or lower than it.