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Monodisperse Colloidal Gallium Nanoparticles: Synthesis, Low Temperature Crystallization, Surface Plasmon Resonance and Li-Ion Storage

Overview of attention for article published in Journal of the American Chemical Society, August 2014
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Title
Monodisperse Colloidal Gallium Nanoparticles: Synthesis, Low Temperature Crystallization, Surface Plasmon Resonance and Li-Ion Storage
Published in
Journal of the American Chemical Society, August 2014
DOI 10.1021/ja506712d
Pubmed ID
Authors

Maksym Yarema, Michael Wörle, Marta D. Rossell, Rolf Erni, Riccarda Caputo, Loredana Protesescu, Kostiantyn V. Kravchyk, Dmitry N. Dirin, Karla Lienau, Fabian von Rohr, Andreas Schilling, Maarten Nachtegaal, Maksym V. Kovalenko

Abstract

We report a facile colloidal synthesis of gallium (Ga) nanoparticles with the mean size tunable in the range of 12-46 nm and with excellent size distribution as small as 7-8%. When stored under ambient conditions, Ga nanoparticles remain stable for months due to the formation of native and passivating Ga-oxide layer (2-3 nm). The mechanism of Ga nanoparticles formation is elucidated using nuclear magnetic resonance spectroscopy and with molecular dynamics simulations. Size-dependent crystallization and melting of Ga nanoparticles in the temperature range of 98-298 K are studied with X-ray powder diffraction, specific heat measurements, transmission electron microscopy, and X-ray absorption spectroscopy. The results point to delta (δ)-Ga polymorph as a single low-temperature phase, while phase transition is characterized by the large hysteresis and by the large undercooling of crystallization and melting points down to 140-145 and 240-250 K, respectively. We have observed size-tunable plasmon resonance in the ultraviolet and visible spectral regions. We also report stable operation of Ga nanoparticles as anode material for Li-ion batteries with storage capacities of 600 mAh g(-1), 50% higher than those achieved for bulk Ga under identical testing conditions.

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The data shown below were collected from the profile of 1 X user who shared this research output. Click here to find out more about how the information was compiled.
Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 217 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Russia 2 <1%
Netherlands 1 <1%
United States 1 <1%
Switzerland 1 <1%
Unknown 212 98%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 63 29%
Researcher 34 16%
Student > Master 27 12%
Student > Bachelor 13 6%
Student > Doctoral Student 11 5%
Other 32 15%
Unknown 37 17%
Readers by discipline Count As %
Chemistry 78 36%
Materials Science 37 17%
Physics and Astronomy 25 12%
Engineering 10 5%
Chemical Engineering 8 4%
Other 9 4%
Unknown 50 23%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 25 August 2014.
All research outputs
#17,310,527
of 25,410,626 outputs
Outputs from Journal of the American Chemical Society
#60,037
of 66,587 outputs
Outputs of similar age
#148,104
of 247,209 outputs
Outputs of similar age from Journal of the American Chemical Society
#411
of 557 outputs
Altmetric has tracked 25,410,626 research outputs across all sources so far. This one is in the 21st percentile – i.e., 21% of other outputs scored the same or lower than it.
So far Altmetric has tracked 66,587 research outputs from this source. They typically receive a little more attention than average, with a mean Attention Score of 7.2. This one is in the 6th percentile – i.e., 6% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 247,209 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 31st percentile – i.e., 31% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 557 others from the same source and published within six weeks on either side of this one. This one is in the 18th percentile – i.e., 18% of its contemporaries scored the same or lower than it.