↓ Skip to main content

Gold(I) Catalysis at Extreme Concentrations Inside Self‐Assembled Nanospheres

Overview of attention for article published in Angewandte Chemie. International Edition, September 2014
Altmetric Badge

Mentioned by

twitter
1 X user

Readers on

mendeley
84 Mendeley
You are seeing a free-to-access but limited selection of the activity Altmetric has collected about this research output. Click here to find out more.
Title
Gold(I) Catalysis at Extreme Concentrations Inside Self‐Assembled Nanospheres
Published in
Angewandte Chemie. International Edition, September 2014
DOI 10.1002/anie.201406415
Pubmed ID
Authors

Rafael Gramage‐Doria, Joeri Hessels, Stefan H. A. M. Leenders, Oliver Tröppner, Maximilian Dürr, Ivana Ivanović‐Burmazović, Joost N. H. Reek

Abstract

Homogeneous transition-metal catalysis is a crucial technology for the sustainable preparation of valuable chemicals. The catalyst concentration is usually kept as low as possible, typically at mM or μM levels, and the effect of high catalyst concentration is hardly exploited because of solubility issues and the inherent unfavorable catalyst/substrate ratio. Herein, a self-assembly strategy is reported which leads to local catalyst concentrations ranging from 0.05 M to 1.1 M, inside well-defined nanospheres, whilst the overall catalyst concentration in solution remains at the conventional mM levels. We disclose that only at this high concentration, the gold(I) chloride is reactive and shows high selectivity in intramolecular CO and CC bond-forming cyclization reactions.

X Demographics

X Demographics

The data shown below were collected from the profile of 1 X user who shared this research output. Click here to find out more about how the information was compiled.
Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 84 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Netherlands 2 2%
France 2 2%
Unknown 80 95%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 20 24%
Student > Master 14 17%
Researcher 10 12%
Student > Bachelor 8 10%
Student > Doctoral Student 5 6%
Other 17 20%
Unknown 10 12%
Readers by discipline Count As %
Chemistry 69 82%
Materials Science 2 2%
Medicine and Dentistry 1 1%
Biochemistry, Genetics and Molecular Biology 1 1%
Computer Science 1 1%
Other 1 1%
Unknown 9 11%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 12 September 2014.
All research outputs
#22,759,802
of 25,374,917 outputs
Outputs from Angewandte Chemie. International Edition
#45,811
of 49,995 outputs
Outputs of similar age
#218,572
of 255,373 outputs
Outputs of similar age from Angewandte Chemie. International Edition
#580
of 721 outputs
Altmetric has tracked 25,374,917 research outputs across all sources so far. This one is in the 1st percentile – i.e., 1% of other outputs scored the same or lower than it.
So far Altmetric has tracked 49,995 research outputs from this source. They typically receive more attention than average, with a mean Attention Score of 7.8. This one is in the 1st percentile – i.e., 1% of its peers scored the same or lower than it.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 255,373 tracked outputs that were published within six weeks on either side of this one in any source. This one is in the 1st percentile – i.e., 1% of its contemporaries scored the same or lower than it.
We're also able to compare this research output to 721 others from the same source and published within six weeks on either side of this one. This one is in the 1st percentile – i.e., 1% of its contemporaries scored the same or lower than it.