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Single-Crystal to Single-Crystal Transformation of a Nonporous Fe(II) Metal–Organic Framework into a Porous Metal–Organic Framework via a Solid-State Reaction

Overview of attention for article published in Inorganic Chemistry, September 2017
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About this Attention Score

  • Above-average Attention Score compared to outputs of the same age (62nd percentile)
  • High Attention Score compared to outputs of the same age and source (80th percentile)

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7 X users

Citations

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18 Dimensions

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31 Mendeley
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Title
Single-Crystal to Single-Crystal Transformation of a Nonporous Fe(II) Metal–Organic Framework into a Porous Metal–Organic Framework via a Solid-State Reaction
Published in
Inorganic Chemistry, September 2017
DOI 10.1021/acs.inorgchem.7b01818
Pubmed ID
Authors

Sebastian Spirkl, Maciej Grzywa, Stephan Reschke, Jonas K. H. Fischer, Pit Sippel, Serhiy Demeshko, Hans-Albrecht Krug von Nidda, Dirk Volkmer

Abstract

We report the synthesis of an air-stable nonporous coordination compound based on iron(II) centers, formate anions, and a 4,4'-bipyrazole (H2BPZ) ligand. Upon thermal treatment, a porous metal-organic framework (MOF) formed due to decomposition of the incorporated formate anions. This decomposition step and the following structural changes constituted a single-crystal to single-crystal transformation. The resulting [Fe(BPZ)] framework contained tetrahedrally coordinated iron(II) metal centers. The framework was sensitive toward oxidation by molecular oxygen even at temperatures of 183 K, as followed by oxygen sorption measurements and a color change from colorless to metallic black. The semiconductor properties of the oxidized material were studied by diffuse reflectance UV/vis/NIR spectroscopy and dielectric spectroscopy.

X Demographics

X Demographics

The data shown below were collected from the profiles of 7 X users who shared this research output. Click here to find out more about how the information was compiled.
Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 31 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 31 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 12 39%
Researcher 5 16%
Student > Doctoral Student 4 13%
Student > Master 3 10%
Professor 2 6%
Other 2 6%
Unknown 3 10%
Readers by discipline Count As %
Chemistry 19 61%
Engineering 2 6%
Chemical Engineering 1 3%
Social Sciences 1 3%
Physics and Astronomy 1 3%
Other 2 6%
Unknown 5 16%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 4. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 04 November 2017.
All research outputs
#7,783,218
of 24,176,645 outputs
Outputs from Inorganic Chemistry
#4,893
of 22,745 outputs
Outputs of similar age
#119,663
of 324,669 outputs
Outputs of similar age from Inorganic Chemistry
#63
of 350 outputs
Altmetric has tracked 24,176,645 research outputs across all sources so far. This one has received more attention than most of these and is in the 67th percentile.
So far Altmetric has tracked 22,745 research outputs from this source. They receive a mean Attention Score of 2.8. This one has done well, scoring higher than 77% of its peers.
Older research outputs will score higher simply because they've had more time to accumulate mentions. To account for age we can compare this Altmetric Attention Score to the 324,669 tracked outputs that were published within six weeks on either side of this one in any source. This one has gotten more attention than average, scoring higher than 62% of its contemporaries.
We're also able to compare this research output to 350 others from the same source and published within six weeks on either side of this one. This one has done well, scoring higher than 80% of its contemporaries.