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S-Benzyl 3-[1-(6-methyl­pyridin-2-yl)ethyl­idene]di­thio­carbazate: crystal structure and Hirshfeld surface analysis

Overview of attention for article published in Acta Crystallographica Section E: Crystallographic Communications, January 2018
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Title
S-Benzyl 3-[1-(6-methyl­pyridin-2-yl)ethyl­idene]di­thio­carbazate: crystal structure and Hirshfeld surface analysis
Published in
Acta Crystallographica Section E: Crystallographic Communications, January 2018
DOI 10.1107/s2056989018001330
Pubmed ID
Authors

S.A. Omar, C.K. Chah, T.B.S.A. Ravoof, M.M. Jotani, E.R.T. Tiekink

Abstract

In the title di-thio-carbazate ester, C16H17N3S2 (systematic name: (Z)-{[(benzyl-sulfan-yl)methane-thio-yl]amino}[1-(6-methyl-pyridin-2-yl)ethyl-idene]amine), the central methyl-idenehydrazinecarbodi-thio-ate (C2N2S2) core is almost planar (r.m.s. deviation = 0.0111 Å) and forms dihedral angles of 71.67 (3)° with the approximately orthogonally inclined thio-ester phenyl ring, and 7.16 (7)° with the approximately coplanar substituted pyridyl ring. The latter arrangement and the Z configuration about the imine-C=N bond allows for the formation of an intra-molecular hydrazine-N-H⋯N(pyrid-yl) hydrogen bond that closes an S(6) loop. In the crystal, phenyl-C-H⋯S(thione), methyl-ene-C-H⋯π(pyrid-yl), methyl-ene- and phenyl-C-H⋯π(phen-yl) contacts connect mol-ecules into supra-molecular layers propagating in the bc plane; the layers stack along the a axis with no directional inter-actions between them. The analysis of the Hirshfeld surface indicates the relative importance of an intra-layer phenyl-H⋯H(pyrid-yl) contact upon the mol-ecular packing.

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Unknown 1 100%

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Readers by professional status Count As %
Student > Master 1 100%
Readers by discipline Count As %
Chemistry 1 100%
Attention Score in Context

Attention Score in Context

This research output has an Altmetric Attention Score of 1. This is our high-level measure of the quality and quantity of online attention that it has received. This Attention Score, as well as the ranking and number of research outputs shown below, was calculated when the research output was last mentioned on 29 June 2018.
All research outputs
#20,439,137
of 25,992,468 outputs
Outputs from Acta Crystallographica Section E: Crystallographic Communications
#1
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Outputs of similar age
#329,722
of 453,331 outputs
Outputs of similar age from Acta Crystallographica Section E: Crystallographic Communications
#1
of 1 outputs
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