Chapter title |
Rearrangements Induced by Hypervalent Iodine
|
---|---|
Chapter number | 657 |
Book title |
Hypervalent Iodine Chemistry
|
Published in |
Topics in current chemistry, January 2015
|
DOI | 10.1007/128_2015_657 |
Pubmed ID | |
Book ISBNs |
978-3-31-933731-9, 978-3-31-933733-3
|
Authors |
Gaëtan Maertens, Sylvain Canesi |
Abstract |
This chapter describes advances in hypervalent iodine(III)-induced rearrangements reported between 2004 and 2015, beginning with Hofmann-type rearrangements and aliphatic aryl transpositions. In both reactions the iodine(III) reagent may be off-the-shelf or catalytically generated in situ. A number of stereoselective transformations are discussed, followed by transpositions triggered through phenol dearomatization, including Wagner-Meerwein-type rearrangements, Prins-pinacol transpositions, and a tandem polycylization-pinacol process. Other rearrangements such as an iodonio-Claisen rearrangement, an ipso-rearrangement, and rearrangements performed using iodine(V) are also described. |
Mendeley readers
Geographical breakdown
Country | Count | As % |
---|---|---|
Unknown | 8 | 100% |
Demographic breakdown
Readers by professional status | Count | As % |
---|---|---|
Student > Ph. D. Student | 2 | 25% |
Student > Doctoral Student | 2 | 25% |
Lecturer | 1 | 13% |
Professor | 1 | 13% |
Unknown | 2 | 25% |
Readers by discipline | Count | As % |
---|---|---|
Chemistry | 6 | 75% |
Unknown | 2 | 25% |