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Hypervalent Iodine Chemistry

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Attention for Chapter 657: Rearrangements Induced by Hypervalent Iodine
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Chapter title
Rearrangements Induced by Hypervalent Iodine
Chapter number 657
Book title
Hypervalent Iodine Chemistry
Published in
Topics in current chemistry, January 2015
DOI 10.1007/128_2015_657
Pubmed ID
Book ISBNs
978-3-31-933731-9, 978-3-31-933733-3
Authors

Gaëtan Maertens, Sylvain Canesi

Abstract

This chapter describes advances in hypervalent iodine(III)-induced rearrangements reported between 2004 and 2015, beginning with Hofmann-type rearrangements and aliphatic aryl transpositions. In both reactions the iodine(III) reagent may be off-the-shelf or catalytically generated in situ. A number of stereoselective transformations are discussed, followed by transpositions triggered through phenol dearomatization, including Wagner-Meerwein-type rearrangements, Prins-pinacol transpositions, and a tandem polycylization-pinacol process. Other rearrangements such as an iodonio-Claisen rearrangement, an ipso-rearrangement, and rearrangements performed using iodine(V) are also described.

Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 8 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Unknown 8 100%

Demographic breakdown

Readers by professional status Count As %
Student > Ph. D. Student 2 25%
Student > Doctoral Student 2 25%
Lecturer 1 13%
Professor 1 13%
Unknown 2 25%
Readers by discipline Count As %
Chemistry 6 75%
Unknown 2 25%